Spectral observation of conversion between ionized vs. non-ionized proton-coupled electron transfer interfaces.

نویسندگان

  • Elizabeth R Young
  • Joel Rosenthal
  • Daniel G Nocera
چکیده

Two-point hydrogen bonding between acid and base functionalities provides a convenient method for the modular assembly of proton-coupled electron transfer (PCET) networks, especially when that interface comprises an amidinium and two-point anionic partner; a system is presented that permits the proton configuration within the interface to be determined when pK(a) values of the conjugate acids are known.

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عنوان ژورنال:
  • Chemical communications

دوره 20  شماره 

صفحات  -

تاریخ انتشار 2008